However, frontman, Caleb Followill, has confirmed that if Daniel were to ask again, they may reconsider.

Caleb said:  "I've always wanted to work with strings so that would be a good excuse to do it."

Drummer Nathan added:  "Hmm Daniel Craig has asked me before. I have turned him down 3 times already but maybe."

In the Twitter conversation with Vue Cinemas, Caleb and Nathan were also asked which actor would they want to play them in a film.  Caleb replied, “Obviously Brad Pitt – hello!” whilst Nathan went for the ‘Honey I Shrunk The Kid star, “Rick Moranis - little geeky glasses, charming you know.”

The band performed at London's Hyde Park last night.

Watch an interview with Stephen Mitchell, Director of Kings of Leon documentary, 'Talihina Sky', below: